Examination of soil values with regard to protection of soil organisms and validation of soil assessment methods

In this project, recommendations for precautionary values are given for 16 metals and ten organics, which were derived on the basis of ecotoxicological tests performed with soil organisms. In the case of three substances (antimony, beryllium, vanadium) the amount of data was not sufficient for such a derivation, while for the metals arsenic, lead, cadmium, chromium, cobalt, copper, molybdenum, nickel, mercury, selenium, thallium, uranium, zinc and the organics benzo[a]pyrene (BaP), 3,4-dichloroaniline (DCA), 2,4-dichlorophenol (DCP), 1,1-bis(4-chlorphenyl)-2,2,2-trichlorethan (DDT), hexachlorocyclohexane (HCH), linear alcylbenzolsulfonic acid and -sulfonate (LAS), polycyclic aromatic hydrocarbons (PAH), pentachlorophenol (PCP), tributyltin (TBT) and trinitrotoluol (TNT), detailed proposals could be made. All recommended values were examined in a plausibility check, which focussed on similar values derived in other countries, for those substances with no existing precautionary value also regarding the background values in Germany. In contrast to previous projects where EC50 values were used, the present calculations are based on NOEC/EC10 values. Therefore, these values do not refer to the level of harm but to the level of precaution (soil values derived from EC50 values correspond to trigger values). It is recommended to close the identified data gaps in order to improve the derivation of precautionary values. Thus, in particular soil invertebrates should be tested in standard tests, but using species not yet included in the standard test guidelines.